2-Indanone 615-13-4 CAS NO.615-13-4

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Introduction:

2-Indanone Basic information

Uses Preparation

Product Name:	2-Indanone
Synonyms:	1,3-dihydro-2h-inden-2-on;1,3-Dihydro-2H-inden-2-one;2H-Inden-2-one,1,3-dihydro-;2-Hydrindone;2-Oxohydrindene;2-INDANONE;INDANONE(2-);Indan-2-one
CAS:	615-13-4
MF:	C9H8O
MW:	132.16
EINECS:	210-410-3
Product Categories:	Indane/Indanone and Derivatives;Indanone & Indene;Carbonyl Compounds
Mol File:	615-13-4.mol

2-Indanone Chemical Properties

Melting point	51-54 °C (lit.)
Boiling point	218°C
density	1.0712
refractive index	1.5380 (estimate)
Fp	212 °F
storage temp.	2-8°C
solubility	Chloroform (Slightly), Ethyl Acetate (Slightly)
form	Crystals or Powder
color	Light yellow to yellow-brown
Odor Threshold	0.00036ppm
Water Solubility	insoluble
Sensitive	Hygroscopic
BRN	636550
InChIKey	UMJJFEIKYGFCAT-UHFFFAOYSA-N
CAS DataBase Reference	615-13-4(CAS DataBase Reference)
NIST Chemistry Reference	2H-inden-2-one, 1,3-dihydro-(615-13-4)
EPA Substance Registry System	2-Indanone (615-13-4)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	22-24/25-36-26
WGK Germany	3
RTECS	NK7535500
F	3
Hazard Note	Irritant
TSCA	Yes
HS Code	29145090

MSDS Information

Provider	Language
2-Indanone	English
SigmaAldrich	English
ACROS	English
ALFA	English

2-Indanone Usage And Synthesis

Uses	2-Indanone is an indanone with an oxo substituent at position 2. It is a metabolite of indane. It has a role as a xenobiotic metabolite. 2-Indanone is an intermediate for the preparation of aprindine hydrochloride and ceforanide. It is an important intermediate in organic synthesis.
Preparation	2-Indanone is prepared by using acetic acid as solvent, acetic anhydride as catalyst and through hydrogen peroxide oxidation into 1, 2-indenediol, which reacted with dilute sulfuric acid solution in order to obtain crude 2-indanone. Finally, vacuum sublimation to obtain 2-indanone with high-purity, the total yield is 89%.
Chemical Properties	Wet crystalline aggregates
Uses	2-Indanone undergoes TiCl4-Mg mediated coupling with CHBr3 to yield dibromomethyl carbinol. It reacts with 5,5-dimethyl-3-pyrazolidinone to yield 5,5-dimethyl-2-(1H-indenyl-2)-3-pyrazolidinone. On photolysis by 266-nm one-photon excitation yields o-xylylene. It was used as starting reagent in the synthesis of indene-fused porphyrins.
Definition	ChEBI: An indanone with an oxo substituent at position 2. It is a metabolite of indane.
Synthesis Reference(s)	Chemistry Letters, 11, p. 325, 1982 Organic Syntheses, Coll. Vol. 5, p. 647, 1973 Tetrahedron Letters, 15, p. 3789, 1974 DOI: 10.1016/S0040-4039(01)92010-6
General Description	2-Indanone undergoes TiCl4-Mg mediated coupling with CHBr3 to yield dibromomethyl carbinol. It reacts with 5,5-dimethyl-3-pyrazolidinone to yield 5,5-dimethyl-2-(1H-indenyl-2)-3-pyrazolidinone. 2-Indanone on photolysis by 266-nm one-photon excitation yields o-xylylene.

2-Indanone Preparation Products And Raw materials

Preparation Products

DELAPRIL-->3-ISOCHROMANONE-->Indan-2-amine

 

 

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